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Tm2O3掺杂浓度对锗酸盐玻璃热稳定性及光谱性质的影响

Influences of Tm2O3 Doping Concentration on Thermal Stability and Spectroscopic Properties of Germanate Glass

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摘要

用高温熔融法制备了Tm2O3掺杂的55GeO2-15PbO-5PbF2-10BaO-10ZnO-5K2O锗酸盐玻璃,测试了该玻璃的热稳定性和结构,得到其热稳定性参数大于180 ℃。通过红外光谱测试了该玻璃的羟基含量,得到羟基吸收系数小于0.51 cm-1。测试了不同Tm2O3掺杂浓度下样品的吸收光谱和荧光光谱。研究结果表明,随着Tm2O3质量分数的增加,Tm3+之间的交叉弛豫速率增大。当Tm2O3的质量分数为5%时,1880 nm处的荧光强度最强, 3F4到3H6能级跃迁的峰值发射截面高达5.84×10-21 cm2。

Abstract

The Tm2O3-doped 55GeO2-15PbO-5PbF2-10BaO-10ZnO-5K2O germanate glass is fabricated by using the high temperature melt-quenching method. The thermal stability and structures of this glass are measured, and the thermal stability coefficient of this glass is greater than 180 ℃. The hydroxyl content of this glass is measured by a infrared spectroscopy and the hydroxyl absorption coefficient is less than 0.51 cm-1. The absorption and fluorescence spectra are obtained under different Tm2O3 doping concentrations. The research results show that the cross-relaxation rate increases with the increase of Tm2O3 mass fraction. When the mass fraction of Tm2O3 is 5%, the fluorescence intensity at a wavelength of 1880 nm reaches the maximum, and the peak emission cross section of 3F4→3H6 energy transition is up to 5.84×10-21 cm2.

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中图分类号:TQ171

DOI:10.3788/cjl201845.0603001

所属栏目:材料与薄膜

收稿日期:2017-12-27

修改稿日期:2018-01-25

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焦孟珺:中国科学院上海光学精密机械研究所高功率单元技术研发中心, 上海 201800中国科学院大学, 北京 100049中国科学院上海光学精密机械研究所强激光材料重点实验室, 上海 201800
王欣:中国科学院上海光学精密机械研究所高功率单元技术研发中心, 上海 201800中国科学院上海光学精密机械研究所强激光材料重点实验室, 上海 201800
胡丽丽:中国科学院上海光学精密机械研究所高功率单元技术研发中心, 上海 201800中国科学院上海光学精密机械研究所强激光材料重点实验室, 上海 201800

联系人作者:胡丽丽([email protected])

备注:焦孟珺(1992—),女,硕士研究生,主要从事掺铥锗酸盐激光玻璃方面的研究。E-mail: [email protected]

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引用该论文

Jiao Mengjun,Wang Xin,Hu Lili. Influences of Tm2O3 Doping Concentration on Thermal Stability and Spectroscopic Properties of Germanate Glass[J]. Chinese Journal of Lasers, 2018, 45(6): 0603001

焦孟珺,王欣,胡丽丽. Tm2O3掺杂浓度对锗酸盐玻璃热稳定性及光谱性质的影响[J]. 中国激光, 2018, 45(6): 0603001

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